Aerial Oxidation of Phenol/Catechol in the Presence of Catalytic Amounts of [(Cl)2Mn(RCOOET)], RCOOET= Ethyl-5-Methyl-1-(((6-Methyl-3-Nitropyridin-2-yl)Amino)Methyl)-1H-Pyrazole-3-Carboxylate
نویسندگان
چکیده
In this work, we report on the catalytic activity of a manganese complex [(Cl)2Mn(RCOOET)], where RCOOET is ethyl-5-methyl-1-(((6-methyl-3-nitropyridin-2-yl)amino)methyl)-1H-pyrazole-3-carboxylate, in oxidation phenol or catechol by atmospheric oxygen to form o-quinone. The [(Cl)2Mn(RCOOET)] catalyzes at rate 3.74 µmol L−1 min−1 tetrahydrofuran (THF), similar manner catecholase tyrosinase.
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ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12121642